It can also be used defensively.
For example, say that France is fighting a war against Germany and Italy. France has armies in Marseilles, Burgundy, and Ruhr. Germany has armies in Munich and Silesia. Italy has armies in Tyrolia and Piedmont, and a fleet in the Gulf of Lyon.
Italy wants to take Marseilles. To guarantee this, they need Burgundy's support to be cut. Thus, Germany orders Mun-Bur.
However, France could conceivably attack Munich. To defend against this, the German army in Silesia supports Tyrolia into Munich (as for why Silesia isn't covering Munich, suppose Austria is allied with France and might attack Tyrolia). If France attacks Munich with support, it is bounced out by the supported Italian army. However, since one can not support the dislodging of one's own units, the Italian army can not take Munich either. Munich is safe, unless the Germany army actually leaves it for good (i.e. the move to Burgundy succeeds).