6 colors on a cube (without mixing colors):
there are certainly 6! arrangements possible on the cube, but this does not take into account the symmetries of the cube. allowing only rigid rotations (no reflections to turn the cube "inside out"), we know the rigid symmetries of the cube. they are described by a subgroup of a "Weyl group" - but all that's important for our purposes is how many there are. this is easy to count, playing with a six-sided die: if you roll the die, there are 6 possibilities for the top, which consequently forces the bottom face's value. there are four vertical sides now, one of which can be called the "front" - but this forces the remaining three faces. hence, there are 6*4 rigid symmetries of the cube. taking our 6! colorings and factorizing with respect to these symmetries, (if you can rotate a cube, this doesn't really change its coloring), we get (6!) / (6*4) = 5*3 = 15 colorings. there is perhaps a more elegant interpretation in terms of pairings:
15 counts the number of ways you can sort 6 objects into pairs. all we've done with our colors is pair them (on opposite faces of the cube). we don't care which face they color, only the relationships between them.
unfortunately, this "pairing argument" does not generalize to other shapes - we can check that the tetrahedron allows 2 distinct colorings, but there are 3 ways to pair 4 objects. we can also show that the octahedron allows (8!) / (6*4) distinct colorings, but there are 7*5*3 ways to pair 8 objects. I haven't checked the dodecahedron or icosahedron, but I conjecture that the cube is the only platonic solid that this can work for. anyone care to explain why?